Alexandre VIMONT

Alexandre VIMONT

Ingénieur de recherche
Tel: + 33 (0)2 31 45 13 47
Room: CNRT – 228
Contact

Send a message.

S'il vous plaît patienter ...



[toc]

Activités professionnelles
  • Maintenance et développement du parc de spectromètres infrarouge dédié aux études in situ et operando de catalyseurs et matériaux poreux.
  • Formation d’étudiants et chercheurs à la caracterisation IR : techniques expérimentales et interprétations de données complexes.
Responsabilités exercées
  • Responsable scientifique pour le LCS du projet de recherche NoMAC financé par l’ANR, et portant sur la capture et le stockage du CO2 dans les composés hybrides organiques-inorganiques. (laboratoires partenaires Versailles, Montpellier, Marseille, Institut Français du Pétrole)
  • Responsable scientifique pour le LCS du projet de recherche SHAFS financé par l’ANR, et portant sur l’adsorption de composés polaires ou apolaires dans les composés hybrides organiques-inorganiques. (laboratoires partenaires Versailles, Montpellier, Marseille, Institut Français du Pétrole)
  • Co-responsable scientifique pour le LCS du projet européen STREPS DeSANNS (FP-6) portant sur la conception, la synthèse et les applications de nouveaux adsorbats nanoporeux pour le stockage et la purification du CO2. (laboratoires partenaires : Universités d’Edinbourg, Kosice, Londres, Manchester, Marseille, Montpellier, Prague, Saint-Andrew, Versailles, Institut Français du Pétrole)
  • Co-responsable scientifique pour le LCS du projet européen STREPS FUNFLUOS (FP-6 2003-2007) portant sur l’étude des matériaux fluorés fonctionnalisés. (laboratoires partenaires : Universités de Berlin, Bordeaux, Glasgow, Ljubljana, Londres, Manchester)
Responsabilité interne au laboratoire
  • Correspondant formation du laboratoire (depuis 2006).

 

Thèmes, travaux, recherche
  • Etude par spectroscopie infrarouge in situ et operando de la nature des sites d’adsorption et des interactions adsorbant-adsorbat dans les solides hybrides organiques-inorganiques, les fluorures métalliques, et les oxydes métalliques de forte acidité, incluant les zéolithes.
  • Développement de méthodes d’évaluation qualitatives et quantitatives des groupements hydroxyles et des sites acides d’oxydes métalliques par spectroscopie infrarouge in situ couplée ou non à l’analyse thermogravimétrique.




Bibliographie




Journal Articles
"Metal–organic and covalent organic frameworks as single-site catalysts."
Chem. Soc. Rev. - 46, 11, 3134-3184   DOI : 10.1039/C7CS00033B
S. M. J. Rogge, A. Bavykina, J. Hajek, H. Garcia, A. I. Olivos-Suarez, A. Sepúlveda-Escribano, Alexandre Vimont, Philippe Bazin, F. Kapteijn, Marco Daturi, E. V. Ramos-Fernandez, F. X. Llabrés i Xamena, V. Van Speybroeck, and J. Gascon

"Selective nitrogen capture by porous hybrid materials containing accessible transition metal ion sites."
Nature Materials - 16, 5, 526-531   DOI : 10.1038/nmat4825
Ji Woong Yoon, Hyunju Chang, Seung-Joon Lee, Young Kyu Hwang, Do-young Hong, Su-kyung Lee, Ji sun Lee, Seunghun Jang, Tae-Ung Yoon, Kijeong Kwac, Younsung Jung, Renjith S. Pillai, Florian Faucher, Alexandre Vimont, Marco Daturi, Gérard Férey, Christian Serre, Guillaume Maurin, Youn-Sang Bae, and Jong-San Chang

Journal Articles
"Structural Origin of Unusual CO 2 Adsorption Behavior of a Small-Pore Aluminum Bisphosphonate MOF."
The Journal of Physical Chemistry C - 119, 8, 4208-4216   DOI : 10.1021/jp512596u
Miquel Garcia-Rates, Philip L. Llewellyn, Lucia Gaberová, Stuart R. Miller, Thomas Devic, Jean-Claude Lavalley, Sandrine Bourrelly, Emily Bloch, Yaroslav Filinchuk, Paul A. Wright, Christian Serre, Alexandre Vimont, and Guillaume Maurin

"An advanced approach for measuring acidity of hydroxyls in confined space: a FTIR study of low-temperature CO and 15 N 2 adsorption on MOF samples from the MIL-53(Al) series."
Phys. Chem. Chem. Phys. - 17, 37, 24304-24314   DOI : 10.1039/C5CP04139B
M. Mihaylov, S. Andonova, K. Chakarova, Alexandre Vimont, E. Ivanova, N. Drenchev, and K. Hadjiivanov

"Tuning the properties of the UiO-66 metal organic framework by Ce substitution."
Chem. Commun. - 51, 77, 14458-14461   DOI : 10.1039/C5CC05072C
Farid Nouar, Matthew I. Breeze, Betiana C. Campo, Alexandre Vimont, Guillaume Clet, Marco Daturi, Thomas Devic, Richard I. Walton, and Christian Serre

"Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties."
J. Mater. Chem. A - 3 (7): 3294-3309   DOI : 10.1039/C4TA03992K
Florence Ragon, Betiana Campo, Qingyuan Yang, Charlotte Martineau, Andrew Wiersum, Ana Lago, Vincent Guillerm, Callum Hemsley, Jarrod Eubank, Muthusamy Vishnuvarthan, Francis Taulelle, Patricia Horcajada, Alexandre Vimont, Philip Llewellyn, Marco Daturi, Sabine Devautour-Vinot, Guillaume Maurin, Christian Serre, Thomas Devic, and Guillaume Clet

"Spectroscopic Evidence for Open and Closed Lewis Acid Sites in ZrBEA Zeolites."
The Journal of Physical Chemistry C - 119, 31, 17633-17639   DOI : 10.1021/acs.jpcc.5b02745
Vitaly L. Sushkevich, Alexandre Vimont, Arnaud Travert, and Irina I. Ivanova

"Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates."
Chem. Commun. - 50, 51, 10194-10197   DOI : 10.1039/C5CC02550H
S. Wongsakulphasatch, F. Nouar, J. Rodriguez, L. Scott, Clément Leguillouzer, T. Devic, P. Horcajada, J.-M. Grenèche, P.L. Llewellyn, Alexandre Vimont, Guillaume Clet, Marco Daturi, and C. Serre

Journal Articles
"Unusual IR ring mode splittings for pyridinium species in H3PW12O40 heteropolyacid: involvement of the ?NH internal mode."
RSC Advances - 4 (37): 37-19159   DOI : 10.1039/c4ra01912a
Claude Binet, Arnaud Travert, Marco Daturi, Jean-Claude Lavalley, and Alexandre Vimont

"In situ and post-synthesis control of physicochemical properties of FER-type crystals."
Microporous and Mesoporous Materials - 200, 334-342   DOI : 10.1016/j.micromeso.2014.07.057
Xiaoxin Chen, Totka Todorova, Alexandre Vimont, Valérie Ruaux, Zhengxing Qin, Jean-Pierre Gilson, and Valentin Valtchev

"Porous, rigid metal(III)-carboxylate metal-organic frameworks for the delivery of nitric oxide."
APL Materials - 2 (12): http://scitation.aip.org/content/aip/journal/aplmater/2/12/10.1063/1.4904069 (accessed 02/2015)   DOI : 10.1063/1.4904069
Jarrod Eubank, Paul Wheatley, Gaëlle Lebars, Alistair McKinlay, Hervé Leclerc, Patricia Horcajada, Marco Daturi, Alexandre Vimont, Russell Morris, and Christian Serre

"Effect of the ligand functionalization on the acid–base properties of flexible MOFs."
Microporous and Mesoporous Materials - 195, 197-204   DOI : 10.1016/j.micromeso.2014.04.025
Béatrice Moulin, Fabrice Salles, Sandrine Bourrelly, Philip L. Llewellyn, Thomas Devic, Patricia Horcajada, Christian Serre, Guillaume Clet, Jean-Claude Lavalley, Marco Daturi, Guillaume Maurin, and Alexandre Vimont

Journal Articles
"Isomorphous Substitution in a Flexible Metal-Organic Framework: Mixed-Metal, Mixed-Valent MIL-53 Type Materials."
INORGANIC CHEMISTRY - 52 (14): 8171-8182   DOI : 10.1021/ic400923d
Matthew Breeze, Guillaume Clet, Betiana Campo, Alexandre Vimont, Marco Daturi, Jean-Marc Greneche, Andrew Dent, Franck Millange, and Richard Walton

"Evaluation of MIL-47(V) for CO2-Related Applications."
JOURNAL OF PHYSICAL CHEMISTRY C - 117 (2): 962-970   DOI : 10.1021/jp308525k
Philip Llewellyn, Sandrine Bourrelly, Christelle Vagner, Nicolas Heymans, Herve Leclerc, Aziz Ghoufi, Philippe Bazin, Alexandre Vimont, Marco Daturi, Thomas Devic, Christian Serre, Guy De Weireld, and Guillaume Maurin

"Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal-Organic Frameworks."
CHEMISTRY OF MATERIALS - 25 (9): 1592-1599   DOI : 10.1021/cm304037x
A. McKinlay, J. Eubank, S. Wuttke, B. Xiao, P. Wheadey, Philippe Bazin, J. Lavalley, Marco Daturi, Alexandre Vimont, G. De Weireld, P. Horcajada, C. Serre, and R. Morris

"A rare example of a porous Ca-MOF for the controlled release of biologically active NO."
CHEMICAL COMMUNICATIONS - 49 (71): 7773-7775   DOI : 10.1039/c3cc41987h
Stuart Miller, Elsa Alvarez, Lucie Fradcourt, Thomas Devic, Stefan Wuttke, Paul Wheatley, Nathalie Steunou, Christian Bonhomme, Christel Gervais, Danielle Laurencin, Russell Morris, Alexandre Vimont, Marco Daturi, Patricia Horcajada, and Christian Serre

"A robust amino-functionalized titanium(IV) based MOF for improved separation of acid gases."
CHEMICAL COMMUNICATIONS - 49 (86): 10082-10084   DOI : 10.1039/c3cc45828h
Sebastien Vaesen, Vincent Guillerm, Qingyuan Yang, Andrew Wiersum, Bartosz Marszalek, Barbara Gil, Alexandre Vimont, Marco Daturi, Thomas Devic, Philip Llewellyn, Christian Serre, Guillaume Maurin, and Guy De Weireld

"N/S-Heterocyclic Contaminant Removal from Fuels by the Mesoporous Metal-Organic Framework MIL-100: The Role of the Metal Ion."
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - 135 (26): 9849-9856   DOI : 10.1021/ja403571z
Ben Van de Voorde, Mohammed Boulhout, Frederik Vermoortele, Patricia Horcajada, Denise Cunha, Ji Lee, Jong-San Chang, Emma Gibson, Marco Daturi, Jean-Claude Lavalley, Alexandre Vimont, Isabelle Beurroies, and Dirk De Vos

"Modulating active sites in MOFs for improved Lewis acid or base catalysis."
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY - 245
Frederik Vermoortele, Pieterjan Valvekens, Alexandre Vimont, Veronique Van Speybroeck, and Dirk De Vos

"Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal-Organic Frameworks: The Unique Case of UiO-66(Zr)."
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - 135 (31): 11465-11468   DOI : 10.1021/ja405078u
Frederik Vermoortele, Bart Bueken, Gaelle Le Bars, Ben Van de Voorde, Matthias Vandichel, Kristof Houthoofd, Alexandre Vimont, Marco Daturi, Michel Waroquier, Veronique Van Speybroeck, Christine Kirschhock, and Dirk De Vos


Conférence(s) Invitée(s)
"Some examples for an advanced use of vibrational spectroscopy for (porous) material investigation."
School of Molecular Sieves - Prague,République Tchèque - 2013-03-11
Presented by Marco Daturi with the help of Philippe Bazin, Vanessa Blasin-Aube, Alexandre Vimont, and Christian Serre


Oraux
"Replacing rare earth in FCC catalysts – a scientific approach."
2nd International Conference on Materials for Energy (EnMat II) - Karlsruhe,Allemagne - 2013-05-12
Presented by Ralf Bergstraesser with the help of Stephan Wellach, Sergey Sirotin, Alexandre Vimont, Valentin Valtchev, Jean-Pierre Gilson, and Arnaud Travert

"New porous M4+ (Zr, Ti) based MOFs: from poly-carboxylate to naturally occurring -carboxyphenolate ligands. "
International Zeolite Conference ; 17 eme ; Moscou ; Russie ; 7-12 juillet 2013
Presented by T. Devic with the help of F. Ragon, L. Cooper, P. Pardo, A. Lago, N. Guillou, C. Martineau, C. Serre, Guillaume Clet, Alexandre Vimont, and Marco Daturi

"Replacing Rare Earth in FCC Catalysts by Alkaline Earth. "
International Zeolite Conference ; 17 eme ; Moscou ; Russie ; 7-12 juillet 2013
Presented by Edgar Jordan with the help of Ralf Bergstraesser, Stephan Wellach, Yulia Monakhova, Sergey Sirotin, Alexandre Vimont, Jean-Pierre Gilson, and Arnaud Travert

"Intrinsic monomolecular cracking rates of light alkanes over H-ZSM-5 revealed by operando IR spectroscopy."
Europacat ; 11eme ; Lyon ; France ; 1-6 Septembre 2013
Presented by Arnaud Travert with the help of Haoguang Li, Alexandre Vimont, and Rick WORMSBECHER

Journal Articles
"How Interpenetration Ensures Rigidity and Permanent Porosity in a Highly Flexible Hybrid Solid."
CHEMISTRY OF MATERIALS - 24 (13): 2486-2492   DOI : 10.1021/cm300450x
Meenakshi Dan-Hardi, Hubert Chevreau, Thomas Devic, Patricia Horcajada, Guillaume Maurin, Gerard Ferey, Dmitry Popov, Christian Riekel, Stefan Wuttke, Jean-Claude Lavalley, Alexandre Vimont, Tom Boudewijns, Dirk de Vos, and Christian Serre

"Effect of the organic functionalization of flexible MOFs on the adsorption of CO2."
JOURNAL OF MATERIALS CHEMISTRY - 22 (20): 10266-10273   DOI : 10.1039/c2jm15887f
Thomas Devic, Fabrice Salles, Sandrine Bourrelly, Beatrice Moulin, Guillaume Maurin, Patricia Horcajada, Christian Serre, Alexandre Vimont, Jean-Claude Lavalley, Herve Leclerc, Guillaume Clet, Marco Daturi, Phillip Llewellyn, Yaroslav Filinchuk, and Gerard Ferey

"Comparison of Porous Iron Trimesates Basolite F300 and MIL-100(Fe) As Heterogeneous Catalysts for Lewis Acid and Oxidation Reactions: Roles of Structural Defects and Stability."
ACS CATALYSIS - 2 (10): 2060-2065   DOI : 10.1021/cs300345b
Amarajothi Dhakshinamoorthy, Mercedes Alvaro, Patricia Horcajada, Emma Gibson, Muthusamy Vishnuvarthan, Alexandre Vimont, Jean-Marc Greneche, Christian Serre, Marco Daturi, and Hermenegildo Garcia

"A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal-Organic Frameworks."
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION - 51 (37): 9267-9271   DOI : 10.1002/anie.201204806
V. Guillerm, F. Ragon, M. Dan-Hardi, T. Devic, M. Vishnuvarthan, Betiana Campo, Alexandre Vimont, Guillaume Clet, Q. Yang, G. Maurin, G. Ferey, A. Vittadini, S. Gross, and Christian Serre

"Novel sol-gel prepared zinc fluoride: synthesis, characterisation and acid-base sites analysis."
JOURNAL OF MATERIALS CHEMISTRY - 22 (29): 14587-14593   DOI : 10.1039/c2jm31357j
Ying Guo, Stefan Wuttke, Alexandre Vimont, Marco Daturi, Jean-Claude Lavalley, Katharina Teinz, and Erhard Kemnitz

"MIL-100(V) - A mesoporous vanadium metal organic framework with accessible metal sites."
MICROPOROUS AND MESOPOROUS MATERIALS - 157 (SI): 18-23   DOI : 10.1016/j.micromeso.2011.12.001
Alexandra Lieb, Herve Leclerc, Thomas Devic, Christian Serre, Irene Margiolaki, Fatma Mahjoubi, Ji Lee, Alexandre Vimont, Marco Daturi, and Jong-San Chang

"Tuning the breathing behaviour of MIL-53 by cation mixing."
CHEMICAL COMMUNICATIONS - 48 (82): 10237-10239   DOI : 10.1039/c2cc35348b
Farid Nouar, Thomas Devic, Hubert Chevreau, Nathalie Guillou, Emma Gibson, Guillaume Clet, Marco Daturi, Alexandre Vimont, Jean Greneche, Matthew Breeze, Richard Walton, Philip Llewellyne, and Christian Serre

"Energy-Efficient Dehumidification over Hierachically Porous Metal-Organic Frameworks as Advanced Water Adsorbents."
ADVANCED MATERIALS - 24 (6): 806   DOI : 10.1002/adma.201104084
You-Kyong Seo, Ji Yoon, Ji Lee, Young Hwang, Chul-Ho Jun, Jong-San Chang, Stefan Wuttke, Philippe Bazin, Alexandre Vimont, Marco Daturi, Sandrine Bourrelly, Philip Llewellyn, Patricia Horcajada, Christian Serre, and Gerard Ferey

"Infrared Spectroscopy Investigation of the Acid Sites in the Metal-Organic Framework Aluminum Trimesate MIL-100(Al)."
JOURNAL OF PHYSICAL CHEMISTRY C - 116 (9): 5710-5719   DOI : 10.1021/jp210671t
Christophe Volkringer, Herve Leclerc, Jean-Claude Lavalley, Thierry Loiseau, Gerard Ferey, Marco Daturi, and Alexandre Vimont

"Discovering the Active Sites for C3 Separation in MIL-100(Fe) by Using Operando IR Spectroscopy."
CHEMISTRY-A EUROPEAN JOURNAL - 18 (38): 11959-11967   DOI : 10.1002/chem.201201006
Stefan Wuttke, Philippe Bazin, Alexandre Vimont, Christian Serre, You-Kyong Seo, Young Hwang, Jong-San Chang, Gerard Ferey, and Marco Daturi

"Probing the adsorption performance of the hybrid porous MIL-68(Al): a synergic combination of experimental and modelling tools."
JOURNAL OF MATERIALS CHEMISTRY - 22 (20): 10210-10220   DOI : 10.1039/c2jm15609a
Qingyuan Yang, Sebastien Vaesen, Muthusamy Vishnuvarthan, Florence Ragon, Christian Serre, Alexandre Vimont, Marco Daturi, Guy De Weireld, and Guillaume Maurin


Conférences
"Metal Organic framework with reducible open metal sites: in situ FTIR characterization of Fe2+/Fe3+ cus sites." Paper presented at ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
Alexandre Vimont, Herve Leclerc, S. Wuttke, Philippe Bazin, J-C Lavalley, Marco Daturi, P. Horcajada, C. Serre, and G. Férey


Conférence(s) Invitée(s)
"Capture du CO2 : l’apport de la spectroscopie IR."
XVIII Journées du Groupe Français de Spectroscopie Vibrationnelle - Bordeaux, France - 2012-06-06
Presented by Marco Daturi with the help of Alexandre Vimont, Philippe Bazin, and Christian Serre


Séminaire(s) invité(s)
"Characterisation of the sites and structural modifications by IR spectroscopy."
MACADEMIA Training Workshop on Characterisation of MOFs - Londres,Angleterre - 2012-06-14
Presented by Alexandre Vimont


Oraux
"Discovering the active sites in MIL-100(Fe) for C3 separation by using operando IR spectroscopy. "
MOF 2012 - Edinburgh,Royaume Uni - 2012-09-16
Presented by Marco Daturi with the help of S. Wuttke, Philippe Bazin, Alexandre Vimont, P. Horcajada, C. Serre, G. Férey, Y.K. Seo, Y.K. Hwang, and J.S. Chang

"Exploiting the redox activity and/or the charge-transport properties of (porous) coordination polymers. "
Conference on Metal-Organic Frameworks and Open Framework Compounds ; 3eme ; Edinbourgh ; Ecosse ; 16-19 septembre 2012
Presented by T. Devic with the help of T.L. Nguyen, A. Fateeva, C. Serre, G. Ferey, S. Devautour-Vinot, G. Maurin, Guillaume Clet, Alexandre Vimont, R. Demir-Cakan, M. Morcette, J.M. Tarascon, and P. Auban-Senzier