Frédéric THIBAULT-STARZYK

Frédéric THIBAULT-STARZYK

Directeur de Recherche – Directeur du LCS
Tel: + 33 (0)2 31 45 28 10
Room: Bâtiment C – 220
Contact

Send a message.

Please wait...



Born May 23, 1965 Positions held 2012 Director, Catalysis and Spectrochemistry Laboratory, CNRS, ENSICAEN-University of Caen 2009 Research Director, CNRS 2003-04 Visiting fellow in the Surface Science Group, Prof. Sir David King, Cambridge (UK) 1994 Chargé de Recherche (Research Scientist) in the CNRS 1992-94 postdoc with P.A. Jacobs (Katholieke Universiteit Leuven, Belgium), grant from the EU Human Capital and Mobility Program. 1992 PhD organic chemistry in Caen, with a grant from the National Agency for Research on AIDS (ANRS). Research interests and Key Words Heterogeneous catalysis, Infrared spectroscopy, time resolved chemistry, interface & surface chemistry, zeolites, micro & mesoporous materials Key points & Awards President of the French Zeolite Association (GFZ), 2009-14 Treasurer, Federation of European Zeolite Associations (FEZA), 2012-14 Overseas Fellow, Churchill College, Cambridge, 2004 Prize of the Catalysis Division of the French Chemical Society in 2000 100 publications in peer reviewed journals, 20 invited lectures, 1 book, 3 chapters Board of the International Conference on Operando Spectroscopy Research contracts with Total, Toyota, Degussa-Evonik, IFP, Rhodia, Michelin Commission Member - French National Board for Scientific Research (Comité National; 2004-2008) - Commission of the Belgian Fund for Scientific Research, Flanders (FWO) - French National University Council (CNU; 1999-2003) Education Habilitation à Diriger des Recherches, 1999, Ph. D. 1992 (Caen), Maîtrise (MSc) Organic Chemistry, 1988




Bibliographie




Journal Articles
"Selective response of pyrylium-functionalized nanozeolites in the visible spectrum towards volatile organic compounds."
Sensors and Actuators B: Chemical - 249, 114-122   DOI : 10.1016/j.snb.2017.04.038
Mohamad El Roz, Hussein Awala, Frederic Thibault-Starzyk, and Svetlana Mintova

Journal Articles
"Probing zeolites by vibrational spectroscopies."
Chem. Soc. Rev. - 44, 20, 7262-7341   DOI : 10.1039/C5CS00396B
Silvia Bordiga, Carlo Lamberti, Francesca Bonino, Arnaud Travert, and Frédéric Thibault-Starzyk

"On the mechanism of methanol photooxidation to methylformate and carbon dioxide on TiO 2 : an operando-FTIR study."
Phys. Chem. Chem. Phys. - 17, 17, 11277-11283   DOI : 10.1039/C5CP00726G
Mohamad El-Roz, Philippe Bazin, Marco Daturi, and Frederic Thibault-Starzyk

"Pore Occupancy Changes Water/Ethanol Separation in a Metal-Organic Framework - Quantitative Map of Coadsorption by IR."
The Journal of Physical Chemistry C - 119, 39, 22570-22576   DOI : 10.1021/acs.jpcc.5b07183
Mohamad El-Roz, Philippe Bazin, Tadeja Birsa ?eli?, Nataša Zabukovec Logar, and Frederic Thibault-Starzyk

"Unraveling the mechanism of chemical reactions through thermodynamic analyses: A short review."
Applied Catalysis A: General - 504, 220-227   DOI : 10.1016/j.apcata.2014.12.028
Frédéric Meunier, Julien Scalbert, and Frédéric Thibault-Starzyk

"Speciation of adsorbates on surface of solids by infrared spectroscopy and chemometrics."
Analytica Chimica Acta - 891, 79-89   DOI : 10.1016/j.aca.2015.06.006
Franck Vilmin, Philippe Bazin, Frédéric Thibault-Starzyk, and Arnaud Travert

"Catalytic ozonation with ?-Al2O3 to enhance the degradation of refractory organics in water."
Applied Catalysis A: General - 504, 519-532   DOI : 10.1016/j.apcata.2014.10.037
Jullian Vittenet, Wael Aboussaoud, Julie Mendret, Jean-Stéphane Pic, Hubert Debellefontaine, Nicolas Lesage, Karine Faucher, Marie-Hélène Manero, Frédéric Thibault-Starzyk, Hervé Leclerc, Anne Galarneau, and Stéphan Brosillon


Séminaire(s) invité(s)
"FTIR-spectroscopy for material characterizations and photocatalysis studies."
Institute of Chemistry - Ljubljana,Slovenia - 2015-10-14
Presented by Mohamad El-Roz with the help of Frédéric Thibault-Starzyk


Oraux
"Speciation of adsorbates on surface of solids by operando IR spectroscopy and chemometrics: application to the description of reactivity at the silica / silane interfaces."
Operando V - Deauville,France - 2015-05-17
Presented by Franck Villmin with the help of Ilaria Bottero, Philippe Bazin, Nicolas Malicki, Fabrice Gaboriaud, Frédéric Thibault-Starzyk, and Arnaud Travert

Journal Articles
"Infrared study of the silica/silane reaction. Part II."
KGK Kautschuk, Gummi, Kunststoffe - 67, 5, 53-57
Anke Blume, Mohamad El-Roz, and Frédéric Thibault-Starzyk

"Liquid phase cyclohexene oxidation over vanadia based catalysts with tert-butyl hydroperoxide: Epoxidation versus allylic oxidation."
Journal of Molecular Catalysis A: Chemical - 394, 89-96   DOI : 10.1016/j.molcata.2014.07.002
Sanaa El-Korso, Ilyes Khaldi, Sumeya Bedrane, Abderrahim Choukchou-Braham, Frédéric Thibault-Starzyk, and Redouane Bachir

"Ultra-fast framework stabilization of Ge-rich zeolites by low-temperature plasma treatment."
CHEMICAL SCIENCE - 5 (1): 68-80   DOI : 10.1039/c3sc51892b
Mohamad El-Roz, Louwanda Lakiss, Aurelie Vicente, Krassimir Bozhilov, Frédéric Thibault-Starzyk, and Valentin Valtchev

"Ethanol condensation to butanol at high temperatures over a basic heterogeneous catalyst: How relevant is acetaldehyde self-aldolization?"
Journal of Catalysis - 311, 28-32. http://linkinghub.elsevier.com/retrieve/pii/S0021951713003813   DOI : 10.1016/j.jcat.2013.11.004
Scalbert Julien, Frederic Thibault-Starzyk, Jacquot Roland, Morvan Didier, and Frederic Meunier

"The Oil Shale Transformation in the Presence of an Acidic BEA Zeolite under Microwave Irradiation."
Energy & Fuels - 28, 4, 2365-2377   DOI : 10.1021/ef4023898
Ana Neto, Sébastien Thomas, Gary Bond, Frédéric Thibault-Starzyk, Ribeiro Ribeiro, and Carlos Henriques

"Reactivity of Bis[3-(triethoxysilyl)propyl] Tetrasulfide (TESPT) Silane Coupling Agent over Hydrated Silica: Operando IR Spectroscopy and Chemometrics Study."
The Journal of Physical Chemistry C - 118, 8, 4056-4071   DOI : 10.1021/jp408600h
Ilaria Bottero, Franck Vilmin, Arnaud Travert, Nicolas Malicki, Fabien Gaboriaud, Aurélien Trivella, and Frédéric Thibault-Starzyk


Conférence(s) Invitée(s)
"Operando IR for plasma on zeolites: finding new ways for preparation and catalysis."
FEZA ; 6eme ; Leipzig ; Germany ; 8 - 11 Septembre 2014
Presented by Frédéric THIBAULT-STARZYK


Oraux
"Infrared study of the silica / silane reaction."
11th Fall Rubber Colloquium - Hanover,Germany - 2014-11-26
Presented by Blume Anke with the help of Frédéric Thibault-Starzyk, and Mohamad El-Roz

"Photooxydation du méthanol sur TiO2 : étude des mécanismes par couplage SSITKA / IR operando."
Gecat ; 46 eme ; Cluny ; 10-15 mai 2014
Presented by Mohamad El-Roz with the help of Philippe Bazin, Marco Daturi, and Frédéric Thibault-Starzyk

"Surface Intermediates in Photocatalysis or in Plasma Assisted Catalysis by Operando Infrared Spectroscopy."
European Conference on Materials and Technologies for Sustainable Growth - ,Sloveni - 2014-09-19
Presented by Frédéric THIBAULT-STARZYK with the help of Mohamad El-Roz

Journal Articles
"Catalytic CO2 valorization into CH4 on Ni-based ceria-zirconia. Reaction mechanism by operando IR spectroscopy."
CATALYSIS TODAY - 215, 201-207   DOI : 10.1016/j.cattod.2013.02.019
P. Aldana, F. Ocampo, K. Kobl, B. Louis, Frédéric Thibault-Starzyk, Marco Daturi, Philippe Bazin, Sebastien Thomas, and A. Roger

"Infrared Study of the Silica/Silane Reaction."
KGK-KAUTSCHUK GUMMI KUNSTSTOFFE - 66 (10): 63-70
A. Blume, Mohamad El-Roz, and Frédéric Thibault-Starzyk

"Study of Hydrothermal Stability and Water Sorption Characteristics of 3-Dimensional Zn-Based Trimesate."
JOURNAL OF PHYSICAL CHEMISTRY C - 117 (28): 14608-14617   DOI : 10.1021/jp4036327
Tadeja Celic, Matjaz Mazaj, Nathalie Guillou, Erik Elkaim, Mohamad El-Roz, Frédéric Thibault-Starzyk, Gregor Mali, Mojca Rangus, Tomaz Cendak, Venceslav Kaucic, and Natasa Logar

"An operando-IR study of photocatalytic reaction of methanol on new *BEA supported TiO2 catalyst."
CATALYSIS TODAY - 205, 111-119   DOI : 10.1016/j.cattod.2012.08.023
Mohamad El-Roz, Philippe Bazin, and Frédéric Thibault-Starzyk

"Immobilization of TiO2 nanoparticles on natural Luffa cylindrica fibers for photocatalytic applications."
RSC ADVANCES - 3 (10): 3438-3445   DOI : 10.1039/c2ra22438k
Mohamad El-Roz, Zeinab Haidar, Louwanda Lakiss, Joumana Toufaily, and Frédéric Thibault-Starzyk

"Incorporation of clusters of titanium oxide in Beta zeolite structure by a new cold TiCl4-plasma process: physicochemical properties and photocatalytic activity."
PHYSICAL CHEMISTRY CHEMICAL PHYSICS - 15 (38): 16198-16207   DOI : 10.1039/c3cp52478g
Mohamad El-Roz, Louwanda Lakiss, Jaafar El Fallah, Oleg Lebedev, Frédéric Thibault-Starzyk, and Valentin Valtchev

"Operando Infrared (IR) Coupled to Steady-State Isotopic Transient Kinetic Analysis (SSITKA) for Photocatalysis: Reactivity and Mechanistic Studies."
ACS CATALYSIS - 3 (12): 2790-2798   DOI : 10.1021/cs4006088
Mohamad El-Roz, Philippe Bazin, Marco Daturi, and Frédéric Thibault-Starzyk

"Quantification of silanol sites for the most common mesoporous ordered silicas and organosilicas: total versus accessible silanols."
PHYSICAL CHEMISTRY CHEMICAL PHYSICS - 15 (2): 642-650   DOI : 10.1039/c2cp42811c
Matthias Ide, Mohamad El-Roz, Els De Canck, Aurelie Vicente, Tom Planckaert, Thomas Bogaerts, Isabel Van Driessche, Frederic Lynen, Veronique Van Speybroeck, Frederic Thibault-Starzyk, and Pascal Van Der Voort

"Effective bulk and surface temperatures of the catalyst bed of FT-IR cells used for in situ and operando studies."
PHYSICAL CHEMISTRY CHEMICAL PHYSICS - 15 (19): 7321-7327   DOI : 10.1039/c3cp50442e
Haoguang Li, Mickael Rivallan, Frédéric Thibault-Starzyk, Arnaud Travert, and Frederic Meunier

"In Situ FT-IR Investigation of Etravirine Speciation in Pores of SBA-15 Ordered Mesoporous Silica Material upon Contact with Water."
MOLECULAR PHARMACEUTICS - 10 (2): 567-573   DOI : 10.1021/mp300229q
Randy Mellaerts, Elie Fayad, Guy Van den Mooter, Patrick Augustijns, Mickael Rivallan, Frédéric Thibault-Starzyk, and Johan Martens

"Adsorption of CO2, CH4, and H2O in Zeolite ZSM-5 Studied Using In Situ ATR-FTIR Spectroscopy."
JOURNAL OF PHYSICAL CHEMISTRY C - 117 (33): 16972-16982   DOI : 10.1021/jp4037183
Lindsay Ohlin, Philippe Bazin, Frédéric Thibault-Starzyk, Jonas Hedlund, and Mattias Grahn

"Hardwood lignin pyrolysis in the presence of nano-oxide particles embedded onto natural clinoptilolite."
MICROPOROUS AND MESOPOROUS MATERIALS - 176, 162-167   DOI : 10.1016/j.micromeso.2013.04.005
Nevenka Rajic, Natasa Logar, Aleksander Recnik, Mohamad El-Roz, Frédéric Thibault-Starzyk, Paul Sprenger, Lenka Hannevold, Anne Andersen, and Michael Stocker


Conférence(s) Invitée(s)
"New advances in operando ir: ssitka in photocatalysis: some more 13C on the surface."
“Progress in the kinetics and mechanisms of chemical reactions at the atomic and molecular levels”, journée en l'honneur de F. Garin - Strasbourg,France - 2013-03-19
Presented by Frédéric THIBAULT-STARZYK

"Surface Intermediates?in Photocatalysis?by Operando IR Spectroscopy."
European Conference on Materials and Technologies for Sustainable Growth - EcoMaTech - Bled,Slovenia - 2013-09-19
Presented by Frédéric THIBAULT-STARZYK


Oraux
"IR-operando coupled to SSITKA experiment for studying air photocatalytic purification."
Europacat ; 11eme ; Lyon ; France ; 1-6 Septembre 2013
Presented by Mohamad El-Roz with the help of Philippe Bazin, Marco Daturi, and Frédéric Thibault-Starzyk

"Ultrafast framework stabilization of Ge-rich zeolites by low-temperature plasma treatment."
International Zeolite Conference ; 17 eme ; Moscou ; Russie ; 7-12 juillet 2013
Presented by Mohamad El-Roz with the help of Frédéric Thibault-Starzyk, and Valentin Valtchev


Patent
"Dépôt d’oxyde de Titane nanométrique ."
FR 12 57607 (2013) -
Mohamad El-Roz, Frédéric Thibault-Starzyk, and Valentin Valtchev

Journal Articles
"In situ FTIR studies of propene adsorption over Ag- and Cu-exchanged Y zeolites."
MICROPOROUS AND MESOPOROUS MATERIALS - 147 (1): 10-16   DOI : 10.1016/j.micromeso.2011.04.040
F. Benaliouche, Y. Boucheffa, and Frédéric Thibault-Starzyk

"Cold plasma as environmentally benign approach for activation of zeolite nanocrystals."
MICROPOROUS AND MESOPOROUS MATERIALS - 158, 148-154   DOI : 10.1016/j.micromeso.2012.03.003
Mohamad El-Roz, Louwanda Lakiss, Valentin Valtchev, Svetlana Mintova, and Frédéric Thibault-Starzyk

"New Operando IR Technique to Study the Photocatalytic Activity and Selectivity of TiO2 Nanotubes in Air Purification: Influence of Temperature, UV Intensity, and VOC Concentration."
JOURNAL OF PHYSICAL CHEMISTRY C - 116 (24): 13252-13263   DOI : 10.1021/jp3034819
Mohamad El-Roz, Monika Kus, Pegie Cool, and Frédéric Thibault-Starzyk

"Insights into the Mechanisms of Isopropanol Conversion on ?-Al2O3 by Dielectric Barrier Discharge."
PLASMA PROCESSES AND POLYMERS - 9 (9): 850-854   DOI : 10.1002/ppap.201200021
Mickael Rivallan, Elodie Fourre, Sebastien Aiello, Jean-Michel Tatibouet, and Frédéric Thibault-Starzyk


Conférence(s) Invitée(s)
"Fast Infrared for Catalytic Materials."
Eigth International Conference on Material Sciences (CSM8-ISM5) - Beyrouth,Liban - 2012-05-28
Presented by Frédéric THIBAULT-STARZYK

"Fast Infrared for Heterogeneous Catalysis."
18th Slovenian Chemical Days 2012 - Portoroz,Slovenia - 2012-09-12
Presented by Frédéric THIBAULT-STARZYK

"In situ and operando IR spectroscopy for Heterogeneous Catalysis."
International Symposium on Catalysis and Speciality Chemicals - Tlemcen,Algérie - 2012-09-23
Presented by Frédéric THIBAULT-STARZYK


Oraux
"An Operando-IR study of photocatalytic reaction of methanol on new Beta zeolite supported TiO2 catalyst."
International Congress on Operando Spectroscopy (Operando) ; 4eme ; New York ; USA ; 29 avril-3 mai 2012
Presented by Mohamad El-Roz with the help of Philippe Bazin, and Frédéric Thibault-Starzyk


Book / Book Section
"Infrared Spectroscopy."
In Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity,, 3-48. M. Che, J. Védrine (Eds.), Wiley-VCH Verlag Gmbh & Co KGaA
Frédéric Thibault-Starzyk and Françoise Maugé